Effect of packing parameter on phase diagram of amphiphiles: An off-lattice Gibbs ensemble approach

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Effect of packing parameter on phase diagram of amphiphiles: an off-lattice Gibbs ensemble approach.

We determine the phase diagram of several amphiphilic molecules as a function of the amphiphilic parameter alpha defined as the ratio of the volume of hydrophilic to hydrophobic segments using the Gibbs ensemble Monte Carlo method supplemented by configurational bias scheme. Specifically, we study amphiphilic molecules h(1)t(7), h(2)t(6), and h(3)t(5), for which alpha=0.14, 0.33, and 0.60 respe...

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Phase Diagram of Horizontally Invariant Gibbs States for Lattice Models

We study interfaces between two coexisting stable phases for a general class of lattice models. In particular, we are dealing with the situation where several different interface configurations may enter the competition for the ideal interface between two fixed stable phases. A general method for constructing the phase diagram is presented. Namely, we give a prescription determining which of th...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2007

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.2807240